Phenol Recovery from Dilute Aqueous Solution by Organophilic Pervaporation

来源 :第七届国际分离科学与技术会议(Proceedings of the 7th International Conferen | 被引量 : 0次 | 上传用户:edisonlin123
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  There has been significant interest in applying pervaporation for recovery phenol from wastewater [1].In this paper,poly(ether block amide) (PEBA 2533) symmetric membranes were prepared by dry phase version method with a uniform thickness of 30μm [2].PEBA 2533 membrane was investigated for phenol separation from dilute aqueous solution using pervaporation.The effects of feed concentration (100~10000ppm) and operating temperature (50~80°C) on the separation performance were studied in terms of phenol flux and separation factor of phenol/water.Figure 1 showed that phenol flux increased as its feed concentration rose when the temperature kept unchanged.And such a trend becomes more significant at elevated temperatures.However,when phenol concentration exceeded 8000ppm,the permeation flux reduced.The possible reason was that clustering of phenol molecules due to hydrogen bonding would occur.The effect of feed concentration on the separation factor at various temperature was shown in Figure 2.It has been shown that the separation factor was high at low feed concentration and decreased as the feed concentration increases.The results showed that the membrane performance was affected by phenol concentration,especially at elevated temperatures.At 80°C and 8000ppm(feed concentration),phenol flux reached 0.26kg/(m2 h) and seperation factor kept 30 for PEBA 2533 membrane,which was higher than the reference data [3-5].So PEBA 2533 membrane has great industrial prospect for phenol separation by pervaporation.
其他文献
会议
会议
会议
会议
The emerging ceramic membrane reactor,a process that combines the heterogeneous catalysis reaction with the membrane separation,can retain the ultrafine catalyst particles in situ and make the reactio
会议
Membrane technology is a viable energy-saving alternative for CO2 separation.The blending of polyether such as PEO with a suitable polymer supplied an effective way to improve the performance of CO2 s
会议
Cross-linking has been regarded as an effective method to improve the selectivity of gas separation membrane.However,cross-linking also showed a tendency to decrease the gas permeance.In this study,cr
会议
Integrally skinned polyetherimide(PEI)asymmetric membranes were prepared by the phase inversion process in which the casting solution contained dimethylacetamide (DMAc) as a solvent and PVP as a addit
会议
Emission of gasoline vapor always existed in the petroleum transportation,processing and usage processes,which would cause serious environmental problems and resources loss [1].Membrane technology is
会议
Compared with the conventional ceramic membrane fabricated from oxide particles,nanofiber membranes have the distinctive mesh structure and the nanofibers can divide large voids into smaller ones with
会议