【摘 要】
:
含芳基的共轭有机化合物紫外吸收光谱主要受到重复结构单元数和取代基效应的影响,重复结构单元影响研究,最著名的有蒋明谦提出同系线性规律,对取代基效应的影响用到的参数有
【机 构】
:
湖南科技大学化学化工学院,理论化学与分子模拟教育部重点实验室,分子构效关系湖南省普通高校重点实验室,湖南湘潭411201
论文部分内容阅读
含芳基的共轭有机化合物紫外吸收光谱主要受到重复结构单元数和取代基效应的影响,重复结构单元影响研究,最著名的有蒋明谦提出同系线性规律,对取代基效应的影响用到的参数有基态极性参数σp、σm、σmb、σ|+p|和自由基参数σ*JJ、σ*等.
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