含芳基的共轭有机化合物紫外吸收光谱的定量研究

来源 :第十届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户:roseis
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含芳基的共轭有机化合物紫外吸收光谱主要受到重复结构单元数和取代基效应的影响,重复结构单元影响研究,最著名的有蒋明谦提出同系线性规律,对取代基效应的影响用到的参数有基态极性参数σp、σm、σmb、σ|+p|和自由基参数σ*JJ、σ*等.
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