Methods for asymmetric functionalization of alkenes could offer a simple and powerful strategy for stereoselective construction of complex carbon skeletons.Recently,Engle introduced a series of Pd-catalyzed mono-and di-functionalization reactions of unactivated alkenes with various combination of nucleophiles and electrophiles under the control of an amide-linked aminoquinoline(AQ)directing group.1 Last year,we reported the first enantioselective version of these transformations,a hydrocarbonfunctionalization with C–H nucleophiles,using a newly developed monodentate oxazoline ligand(MOXin)featuring a C3-linked indole side arm.