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一般来说,测试样品中含有自由基会影响核磁共振谱仪的匀场甚至锁场,从而导致所测谱峰峰型很乱甚至是无法分辨,因此利用顺磁共振技术是定性检测自由基时研究人员的常用选择.然而在一定条件下,利用核磁共振方法研究有自由基所参与的反应却有着独特的直观的优势.
核磁共振方法研究苯胺和乙酰丙酮自由基反应
【摘 要】
：
一般来说,测试样品中含有自由基会影响核磁共振谱仪的匀场甚至锁场,从而导致所测谱峰峰型很乱甚至是无法分辨,因此利用顺磁共振技术是定性检测自由基时研究人员的常用选择.然而在一定条件下,利用核磁共振方法研究有自由基所参与的反应却有着独特的直观的优势.
【机 构】
：
东北师范大学化学学院 长春 130021;吉林大学超分子结构与材料国家重点实验室 长春 130012
【出 处】
：
第十八届全国波谱学学术年会
【发表日期】
：
2014年4期
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