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LSGM is one of the most promising electrolyte for SOFC,and plenty of researches have been done to improve the performance of LSGM.In this article,effect of doping Li for the Ga site on the oxide ion conductivity of La0.9Sr0.1Ga0.8Mg0.2O3-δ was investigated,and it was found that doping with Li was effective for enhancing the oxide ion conductivity.Phase formations of samples were characterized by XRD and the results prove the successful doping of Li without forming any secondary phases.