Chloromethylation of Poly (Ether Ether Ketone) to Prepare Quaternized Membranes for Hydroxide Exchan

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  Hydroxide exchange membrane fuel cell (HEMFC) is indicated to have high efficiency and reasonable power density [1,2],and it is potential to solve the cost and durability problems of proton exchange membrane fuel cell (PEMFC),due to many advantages including the high durability of catalysts,the expanding of catalyst categories,the facile kinetics at the cathode and anode,easy water management and the reduced fuel crossover [3,4].Hydroxide exchange membrane (HEM) is one of the key components in HEMFC.A simple method of preparing HEMs is that the chloromethyl group is introduced onto the polymers by the chloromethylation and subsequently the quaternary ammonium hydroxide group is introduced by quaternization and alkalization of chloromethylated polymers.The chloromethylation is the most important step because the degree of chloromethylation (DC) determines the ion exchange capacity of the HEM,which in turn determines the ionic conductivity.
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