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A complex,Ho(NO3)3(C2H5O2N)4?H2O,was synthesized and the thermodynamic properties of the complex were studied.Low temperature heat capacities of the complex were measured with a high-precision automatic adiabatic calorimeter over the temperature range from 80 to 390 K,and the thermodynamic functions(HT?H298.15 and ST?S298.15)were derived from the heat capacity data with temperature interval of 5 K.