Mechanistic Insights into the Solvent and Ligand-Dependency in Cu(Ⅰ)-Catalyzed Allylic Alkylation wi

来源 :第十二届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户：wyt20070210

【摘要】

：

The Suzuki-Miyaura coupling(SMC) with gem-diboryalkane as nucleophile provides a mild and efficient method to construct C(sp3)-C bonds in complex organic compou

【作者】

：

Qi Zhang Bing Wang Jia-Qin Liu Yao Fu Yu-Cheng Wu

【机构】

：

InstituteofIndustry&EquipmentTechnology,HefeiUniversityofTechnology,Hefei230009DepartmentofChemistry

【出处】

：

第十二届全国物理有机化学学术会议

【发表日期】

：

2017年10期

下载到本地 , 更方便阅读

下载此文赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

The Suzuki-Miyaura coupling(SMC) with gem-diboryalkane as nucleophile provides a mild and efficient method to construct C(sp3)-C bonds in complex organic compounds.

其他文献

Mechanistic Insights into Ru-Catalyzed Regioselective Cycloisomerization of Aromatic Homo-and Bis-Ho

　　Metal catalyzed cycloisomerization reactions towards the formation of new C-X bonds(where X = C,O,N etc.)has attracted significant attention in recent years

会议

Mechanistic Insights into the Rh(Ⅱ)-Catalyzed Ring Expansion of Aryl Azides to Access N-heterocycles

　　Recently,the direct amination1 of C-H bonds to construct C-N bonds via metal nitrenes2 catalyzed by transition metal catalysts has attracted significant int

会议

分子共晶材料的设计,组装及光功能调控研究

　　本文介绍了近期在多组分微米/纳米共晶材料的组装及光功能研究。与单组分材料相比，多组分体系具备较多优势，通过不同制备方法(如溶液法，固相法，气相法等)可以得到结构和功能

会议

共晶微米/纳米材料分子组装发光

Computational Studies on the Divergent Reactions between α-Imino Rhodium Carbenoids and 1,3-Diketone

　　The characteristic imine functionality adjacent to the rhodium carbenoid center[1] renders these carbene species especially useful in the synthesis of vario

会议

Computational Insights into the Gold-Catalyzed Hydroamination of Methylenecyclopropanes with Sulfona

　　Transition metal-catalyzed reactions of methylenecyclopropanes(MCPs)have attracted increasing research attention over the past two decades since MCPs have h

会议

Small-Molecule Acceptors Based on CPDT Unit for Nonfullerene Polymer Solar Cells

Polymer solar cells(PSCs) with bulk heterojunction(BHJ) architecture have attracted extensive attention due to their unique advantages such as low processing co

会议

Excited-state proton transfer induced [4+2] and [4+4] photocycloaddition reactions of an oxazolineMe

[4+4] and [4+2] photocycloadditions have not computationally attracted the same level of attention as [2+2] photocycloadditions.Herein we have employed density-

会议

Theoretical Studies of Spin State-Specific [2+2] and [5+2] Photocycloaddition Reactions of N-(1-pent

N-alkenyl maleimides are found to exhibit spin state-specific chemoselectivities for [2+2] and [5+2]photocycloadditions;but,reaction mechanism is still unclear

会议

Mechanistic Study on Ni-Catalyzed Silylation of Aryl Methyl Ethers

Aryl methyl ethers are common building blocks in lignin,their effective functionalization provides a potential way to produce value-added chemicals from biomass

会议

Achieving Strong Positive Cooperativity by Waking up Weak Non-Covalent Interactions

In present work,we have introduced another type of cooperativity which is not-existent in single system,but can be can be waked up or even amplified hundred tim

会议

Mechanistic Insights into the Solvent and Ligand-Dependency in Cu(Ⅰ)-Catalyzed Allylic Alkylation wi

与本文相关的学术论文