【摘 要】
：
Three new supramolecular polymers, [(IP)(H_2SO_4)(H_2O)](1), [(H_2SDC)(BPA)](2) and [Mn(SDC)(IP)_2]_n (3), have been constructed by three modes(rigid IP, rigid
【机 构】
：
College of Chemistry & Chemical Engineering,Shaanxi University of Science & Technology,
论文部分内容阅读
Three new supramolecular polymers, [(IP)(H_2SO_4)(H_2O)](1), [(H_2SDC)(BPA)](2) and [Mn(SDC)(IP)_2]_n (3), have been constructed by three modes(rigid IP, rigid SDC + flexible BPA, rigid IP + rigid SDC). Polymers 1 and 2 are supramolecular structures, assembled by hydrogen bonds and π···π interactions. X-ray structure analysis of 3 shows waved 1D chains which form a 3D supramolecular network by hydrogen bonds and π···π interactions. Solid-state properties of thermal stability, luminescent properties, and X-ray powder diffractions for these crystalline materials have also been investigated, and polymer 3 is considered to be a good stable luminescence material.
Three new supramolecular polymers [(IP) (H_2SO_4) (H_2O)] (1), [(H_2SDC) (BPA)] (2) and [Mn (SDC) (IP) _2] _n by three modes (rigid IP, rigid SDC + flexible BPA, rigid IP + rigid SDC) Polymers 1 and 2 are supramolecular structures, assembled by hydrogen bonds and π · π interactions. X-ray structure analysis of 3 shows waved 1D chains which form a 3D supramolecular network by hydrogen bonds and π · π interactions. Solid-state properties of thermal stability, luminescent properties, and X-ray powder diffractions for these crystalline materials have also been investigated, and polymer 3 is considered to be a good stable luminescence material.
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