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The title compound, {[Ag2(bipy)2(H2O)2]·pydc·2H2O}n (bipy=4,4’-bipyridine, pydc= pyridine-3,5-dicarboxylate), has been synthesized by the reaction of Ag2O with pydc and bipy in CH3OH solution. It crystallizes in the monoclinic system, space group C2/c with a=21.419(8), b=7.515(3), c=18.070(7), β=108.273(6)°, Mr=765.27, V=2761.9(17)3, Z=4, Dc=1.840 g/cm3, F(000)= 1528, μ=1.478 mm-1, the final R=0.0307 and wR=0.0681. The structure determined demonstrated that the Ag(I) is three-coordinated by two nitrogen atoms from bipy and one water molecule, forming a one-dimensional coordination polymer [Ag2(bipy)2(H2O)2]n2n+, which is further linked to generate a two-dimensional layer structure via Ag…Ag attractions.
The title compound, {[Ag2 (bipy) 2 (H2O) 2] · pydc · 2H2O} n (bipy = 4,4’-bipyridine, pydc = pyridine-3,5-dicarboxylate), has been synthesized by the reaction of Ag2O with pydc and bipy in CH3OH solution. It crystallizes in the monoclinic system with space group C2 / c with a = 21.419 (8), b = 7.515 (3), c = 18.070 °, Mr = 765.27, V = 2761.9 (17) 3, Z = 4, Dc = 1.840 g / cm3, F (000) = 1528, μ = 1.478 mm-1, the final R = 0.0307 and wR = 0.0681. The structure of the Ag (I) is three-coordinated by two nitrogen atoms from bipy and one water molecule, forming a one-dimensional coordination polymer [Ag2 (bipy) 2 (H2O) 2] n2n +, which is further linked to generate a two-dimensional layer structure via Ag ... Ag attractions.