Fabrication of three-dimensional WO3/ZnWO4/ZnO multiphase heterojunction system with electron storag

来源 :材料科学技术(英文版) | 被引量 : 0次 | 上传用户:teddy18chen
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
A novel three-dimensional hierarchical WO3 photoelectrode was prepared by solvothermal method,and ZnO was deposited on its surface by electrochemical method.The WO3/ZnWO4/ZnO multiphase-heterojunction photoelectrode was prepared by further annealing treatment to explore the photoinduced cathodic protection (CP) performance.Compared with WO3 and ZnO,the photoinduced CP and electron storage capacity performance of WO3/ZnWO4/ZnO is significantly improved in 3.5% NaCl solution without adding any hole scavenger.The electron storage capacity of the WO3/ZnWO4/ZnO heterojunction makes it possible to continuously protect metallic materials in the dark after switching off the light,which can realize long-term and effective photoinduced CP.
其他文献
学位
随着中国交通基础设施建设的不断完善,跨越深沟峡谷、河流大海的桥梁工程也得到了极大的发展。悬索桥因其跨越能力强、适应性好、造型美观等优点,是国内建设广泛采用的大跨经桥梁建设方案。由于我国南部海域地区桥位环境复杂,在役悬索桥受深海环境影响大,结构构件腐蚀情况严重,且重载交通量大等因素的制约。在役悬索桥通常需要更换吊索、完善防护体系以维护结构的安全运营从而满足日益增长的交通量及适应不断变化大气环境的需求
Multi-principal element alloys usually exhibit outstanding strength and toughness at cryogenic tempera-tures,especially in CrMnFeCoNi and CrCoNi alloys.These remarkable cryogenic properties are attributed to the occurrence of deformation twins,and it is e
Graphene films (GFs) and graphene-reinforced nanocomposite coatings (GNCs) have received unprece-dented attention for corrosion protection because graphene possesses a remarkable chemical inertness and is completely impermeable to aggressive chemicals.How
Anneal hardening has been one of the approaches to improve mechanical properties of solid solution alloys with the face-centered cubic (FCC) structure,whereby a considerable strengthening can be at-tained by annealing of cold-worked alloys below the recry
The capture efficiency describes the capability of a sink,such as a grain boundary (GB),dislocation,and void,to absorb point defects (PDs).The bias defines the difference in capture efficiency between the ab-sorption of a vacancy and dumbbell at a sink.Co
Variant selection under specific applied stresses during precipitation of α plates from prior-β matrix in Ti-6Al-4 V was investigated by 3D phase field simulations.The model incorporates the Burgers transfor-mation path from β to α phase,with consideratio
我国西南地区岩溶分布广泛,隧道施工过程中常发生突水、突泥等地质灾害,如何做好隧道超前预报工作,保障隧道的施工安全是当前重要的研究课题。地质雷达轻便、高效、分辨率高,能够实现隧道短距离目标体的精准探测。瞬变电磁法对低阻体分辨能力好,能实现隧道内含水体圈定和掌子面前方中距离地电结构定性分析。本文依托国家重点研发计划项目“典型覆盖区航空地球物理技术示范与处理解释软件平台开发”之课题“航空地球物理数据综合
随着近年来小汽车保有量以及早修建的高速公路路面破损等问题的逐年增加,高速公路改扩建及养护施工需求逐年增加。由于在施工作业路段常常伴随着行车道减少,使得该路段车辆行驶速度的稳定性相较于正常路段有着明显的下降,严重威胁道路交通安全及运行效率,因而需要对施工路段行车速度进行有效控制。现阶段多采用全车型统一的静态限速方法对施工路段进行速度控制,而由于高速公路一般路段对于不同车辆的限速值的差异以及不同类型车
钢筋混凝土梁在海洋环境中,不仅受到海水的浸泡,还受外荷载作用,且两者长期耦合存在。这两种作用会加速混凝土梁内钢筋的锈蚀,尤其是外侧的箍筋,将会导致混凝土梁强度与刚度退化,进而导致混凝土结构功能丧失,服役寿命降低。碳纤维增强复合材料(以下简称CFRP)网格是碳纤维通过浸润在具有良好耐腐蚀性的树脂中制作而成的一种具有良好耐腐蚀性和整体性能的新型材料。将CFRP网格箍筋代替传统钢箍筋,能够有效的提高钢筋