目的合成偶氮四唑的固态配合物,研究其液相生成反应的热动力学。方法用RD496-CK2000微热量计测定其液相生成反应焓变。结果制备了6种固态含能配合物M(ATZ)(phen)2.nH2O(M=Mn,n=5;M=Co,Ni,n=2;M=Cu,Pb,n=1;M=Zn,n=3;ATZ=5,5′-偶氮四唑,phen=1,10-邻菲啰啉),计算出了它们的液相生成反应的热动力学参数。结论反应条件温和,其液相生成反应焓变均为负值,有利于常温反应。 Aim To synthesize azo-tetrazole solid-state complex and investigate the thermokinetics of its liquid-phase reaction. Methods The enthalpy change of liquid phase reaction was measured by RD496-CK2000 microcalorimeter. Results Six kinds of solid-state energetic complexes M (ATZ) (phen) 2.nH2O (M = Mn, n = 5; M = Co, Ni, n = 2; M = Cu, Pb, = Zn, n = 3; ATZ = 5,5’-azotetrazole and phen = 1,10-phenanthroline) were used to calculate the thermodynamic parameters of their liquid-phase reaction. Conclusion The reaction conditions are mild, and the enthalpy changes of liquid phase reaction are all negative, which is good for the reaction at room temperature.