Glasses with chemical composition of(in mol.%): 26 RF-20 PbO-10 TeO2-43 H3BO3-1 EuO3 (RLTB) were prepared by conven-tional melt quenching method. The Judd-Ofelt intensity parameters Ω2 and Ω6 were obtained from the absorption intensities of 7F0→5D2 and 7F0→5L6 transitions, respectively. In order to overcome the problem of applicability of Judd-Ofelt analysis at room temperature due to the overlapping of the transitions originating from 7F0 and 7F1 levels of Eu3+ ion, the effect of the thermalization on the population of energy lev-els was taken into account. The photoluminescence spectra contained five emission bands originating from the 5D0 metastable state to 7FJ (J=0,1, 2, 3, 4) lower lying states. The decay profiles were found to be single exponential in all the three glasses. The measured lifetimes (τmes) were in good agreement with the calculated lifetimes (τcal) obtained by using the thermally corrected Judd-Ofelt intensity parameters.