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本文研究了硼砂—氢氧化钠介质中(pH= 11 .0) ,钴? 催化过氧化氢氧化桑色素的反应,建立了动力光度法测定痕量钴的新方法.方法灵敏度高,线性范围0 ~0 .1 μg·ml-1 ,检出限为0 .2 ×10 - 10 g·ml- 1 .实测了含钴药品中Co ? 含量,结果令人满意.
In this paper, the reaction of borax-sodium hydroxide (pH = 11.0) and cobalt-catalyzed oxidation of morin by hydrogen peroxide was studied. A new method for the determination of trace cobalt by kinetic spectrophotometry was established. The method has high sensitivity and linear range of 0 ~ 0. 1 μg · ml-1, the detection limit was zero. 2 × 10 - 10 g · ml-1. Measured cobalt content in cobalt-containing drugs, the results are satisfactory.