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研究了AlCl3·6H2O晶体中Cr3+离子的ESR光谱.计算结果(D=-0.03264cm-1,g=1.9709和Δg=-0.00027)和实验值(D=-0.0327(1)cm-1,g=1.977(1))符合得很好.还讨论了AlCl3·6H2O晶体中杂质Cr3+离子的局部结构.
The ESR spectra of Cr3 + ions in AlCl3 · 6H2O crystals were investigated. The calculated results (D = -0.03264cm-1, g = 1.9709 and Δg = -0.00027) and the experimental values (D = -0.0327 (1) cm- 1.977 (1)). The local structure of Cr3 + ions in AlCl3 · 6H2O crystals is also discussed.