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首次利用光照的手段实现了苯基三羰基合锰(I)配合物的去配位作用,得到了芳香化合物———苯.产率高达90%以上,反应的量子产率高达0.5.
For the first time, the de-coordination of phenyltritarbonyl manganese (I) complexes was achieved by means of light irradiation, and the aromatic compound --- benzene was obtained. The yield was over 90% and the quantum yield of the reaction was up to 0.5.