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The confined crystallization behavior ofpolycap-rolactone (PCL) in thin and ultrathin films was studied by AFM (atomic force microscopy). It was found that the crys-talline morphology of PCL depended on the film’s thickness.When the thickness is d>2Rg (radius of gyration), the polymer can crystallize into spherulites; when Rg < d< 2 Rg,a dense-branch morphology and dendrites could be found;when d
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