Shape-controlled synthesis and photocatalytic activity of In_2O_3 nanostructures derived from coordi

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:zzzkkk
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In(BTC)(phen)(H_2O)nanocrystals with controllable morphology and size were successfully obtained by solvothermal method.Hierarchical straw-sheaf-like architectures,nanorods and elongated hexagons have been synthesized by varying the volume ratio of DMF:H_2O:C_2H_5OH.Phase-pure In_2O_3nanocrystals were obtained by the calcination of the precursors without significant alteration of the morphology.The products were characterized by PXRD,SEM,TEM,TGA,IR and gas adsorption measurements.The photocatalytic effect was investigated for the In_2O_3 nanocrystals with different morphology on the degradation of rhodamine B(Rh B)and it was found that the nanorods exhibited the best photocatalytic activity,which shows the degradation efficiency of 94%for 8 h.The results showed that the photocatalytic activity increased with the increase of BET surface area and pore volume. In (BTC) (phen) (H_2O) nanocrystals with controllable morphology and size were successfully obtained by solvothermal method. Hierarchical straw-sheaf-like architectures, nanorods and elongated hexagons have been synthesized by varying the volume ratio of DMF: H_2O: C_2H_5OH. Phase-pure In 2 O 3 nanocrystals were obtained by the calcination of the precursors without significant alteration of the morphology.The products were characterized by PXRD, SEM, TEM, TGA, IR and gas adsorption measurements. The photocatalytic effect was investigated for the In 2 O 3 nanocrystals with different morphology on the degradation of rhodamine B (Rh B) and it was found that the nanorods exhibited the best photocatalytic activity, which shows the degradation efficiency of 94% for 8 h. The results showed that the photocatalytic activity increased with the increase of BET surface area and pore volume.
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