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以新颖的过氧钨酸盐——有机酸配位络合物为催化剂 ,在无溶剂和无相转移剂的条件下 ,用 30 %的过氧化氢氧化环己烯合成己二酸 ,其收率可达 93— 95%。本文讨论了配位体种类及催化剂用量对反应的影响。
Using novel tungstate-organic acid coordination complex as catalyst, cyclohexene was oxidized with 30% hydrogen peroxide to synthesize adipic acid without solvent and without phase transfer agent. Rate up to 93-95%. This article discusses the type of ligand and the amount of catalyst on the reaction.