【摘 要】
：
A Mn(II) picolilato complex Mn(2-C5H4NCOO)2(H2O)2·1/2CH3CN 1 has been synthesized. Crystal of 1 is of monoclinic, space group C2/c with a = 25.6613(3), b = 8.6
【机 构】
：
State Key Laboratory of Structural Chemistry
论文部分内容阅读
A Mn(II) picolilato complex Mn(2-C5H4NCOO)2(H2O)2·1/2CH3CN 1 has been synthesized. Crystal of 1 is of monoclinic, space group C2/c with a = 25.6613(3), b = 8.6357(2), c = 16.8286(2) A, β = 122.835(1)β, V = 3133.47(9) A3, Mr=355.7, Dc = 1.508 g/cm3, F(000) = 1456, μ = 0.874 cm-1 and Z = 8. The final refinement gave R = 0.0362 and wR = 0.1096 for 2264 reflections (I > 2σ(I)). The Mn(II) atom possesses distorted octahedral coordination geometry and the structural parameters around the Mn ion are close to those of other Mn analogues. Extensive hydrogen bonding interactions between carboxylate and H2O were observed making one-dimensional chains of the Mn monomers.
其他文献
Let X denote a complex analytic manifold, and let Aut(X) denote the space of invertible maps of a germ (X, a) to a germ (X, b); this space is obviously a groupo
An elastic stamp was produced by molding poly(dimethylsiloxane)(PDMS) against a master with micropatterns on the surface. Then a procedure named microcontact pr
A novel polypeptide having stimulant effect on some cell proliferation was isolated from the velvet antler (Cervus elaphus Linnaeus). The velvet antler polypep
考虑带有Frobenius范数界的不确定广义系统具有完整性的鲁棒二次稳定问题.通过代数Riccati不等式给出不确定广义系统在状态反馈下所构成的闭环系统鲁棒二次稳定并且当执行器
A new facile route for the synthesis of dl-shikonin is presented. Reformatsky reaction assisted cross-coupling of 1, 4, 5, 8-tetramethoxynaphthalene-2-carbalde
The structure of a Hamiltonian matrix for a quantum chaotic system, the nuclear octupole deformationmodel, has been discussed in detail. The distribution of the
Crystallization in polymer systems actually is a process that transfers the entangled melts into a semi-crystalline layered structure. Whether or not a chain di
This paper presents liner homogeneous model describing two-phase flow instability. Dimensionless parameter η was derived by using the linear homogeneous model.
Objective: To prepare monoclonal antibody (McAb) against the Integrin α6 extracellular domain and identify its biological activities. Methods: Fusion-protein o
Compound 1 as a key intermediate of 1, 7, 9-trideoxytaxol was synthesized in ten steps from a biosynthetically available taxane, Sinenxan A. The key steps in t