In this paper, we present a linear optical scheme for optimal unambiguous discrimination among nonorthogonal quantum states in terms of the multiple-rail and polarization representation of a single photon. In our scheme, discriminated quantum states are expressed by using the spatial degree of freedom of a single photon while the polarization degree of freedom of the single photon is used to act as an auxiliary qubit. The optical components used in our scheme are only passive linear optical elements such as polarizing beam splitters, wave plates, polarizers, single photon detectors,and single photon source.