Shellac-coated iron oxide nanoparticles for removal of cadmium(Ⅱ) ions from aqueous solution

来源 :环境科学学报(英文版) | 被引量 : 0次 | 上传用户:andrew142
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
This study describes a new effective adsorbent for cadmium removal from aqueous solution synthesized by coating a shellac layer,a natural biodegradable and renewable resin with abundant hydroxyl and carboxylic groups,on the surface of iron oxide magnetic nanoparticles.Transmission Electron Microscopy (TEM) imaging showed shellac-coated magnetic nanoparticle (SCMN) adsorbents had a core-shell structure with a core of 20 nm and shell of 5 nm.Fourier Transform Infrared Spectroscopic analysis suggested the occurrence of reaction between carboxyl groups on the SCMN adsorbent surface and cadmium ions in aqueous solution.Kinetic data were well described by pseudo second-order model and adsorption isotherms were fitted with both Langmuir and Freundlich models with maximum adsorption capacity of 18.80 mg/g.SCMN adsorbents provided a favorable adsorption capacity under high salinity conditions,and cadmium could easily be desorbed using mild organic acid solutions at low concentration.
其他文献
泥河湾盆地旧石器时代考古遗址数量多,时间跨度大,地貌和地层清楚,具有丰富的文化内涵。本文根据现有材料和遗址测年数据研究表明盆地从早更新世到晚更新世发现的旧石器时代
Advancing the understanding of the spatial aspects of air pollution in the city regional environment is an area where improved methods can be of great benefit t
《左传》等传世文献中记载有大量薳(蒍)氏家族的信息,南阳淅川发现有(郐)氏家族墓葬,楚简等出土文献中还包含有(蒍)氏家族及遠氏(学界以为即薳氏)家族的信息.结合传世文献及
目的探讨青铜铁器时代、近代人群下颌骨第1磨牙齿冠面4个区域的磨耗特点。方法将青铜铁器时代(大同、陇县共35例)、近代(云南、华北共195例)人群下颌骨第1磨牙齿冠面分为4个
乌兰木伦遗址于2010年发现并进行了首期试掘,在7个文化层位中获得石制品1500余件、动物化石千余件以及人类用火遗迹。初步观察和研究表明,该遗址以石片石器为特点的石制品类
目前古代淀粉粒鉴别的两种方法,即显微镜观察法和碘着色测试法,均不能确保鉴别的准确性.针对耐热性α-淀粉酶只对淀粉产生降解的特点,设计出古代淀粉粒鉴别的“耐热性α-淀粉
A novel dimeric procyanidin glucoside,catechin 3-O-acetate-(4α→8)-catechin 3-O-acetate-3′-O-β-D-glucopyranoside (1),along with five flavonoids and one ligna
Selective hydrogenation of α,β-unsaturated aldehydes with modified Pd/C catalyst was developed.The reduction of C=O bond could be efficiently inhibited by the
A direct decarbonation route without obvious morphology damage was developed for large micrometer-scale layered double hydroxides (LDHs).First,we synthesized pu
A novel magnetic anion exchange resin NDM-1 was prepared through suspension polymerization and then functionalized with ammonolysis and alkylating agents.Its ap