论文部分内容阅读
合成了含有丁腈橡胶 ( NBR)的甲基丙烯酸齐聚氧化乙烯酯 ( MEO12 )与甲基丙烯酸己基磺酸锂 ( SHMAL i)反相共聚胶乳 ,将反相共聚胶乳与聚氯乙烯 ( PVC)溶液共混浇铸成具有多相结构的聚合物膜。这种多相聚合物膜中含有高分子锂盐 ,用增塑剂增塑或吸收无机锂盐有机溶液则成为聚合物单离子导体或双离子导体 ,其室温电导率分别大于 3.0× 1 0 - 4S.cm- 1和 2 .0 6× 1 0 - 3S.cm- 1。膜中增塑的 PVC连续相起到力学支撑体作用 ,因此增塑的多相聚合物离子导体具有大于 9.8× 1 0 5Pa力学强度。
In this paper, an inverse copolymerization latex of MEO12 and SHMAL i was synthesized by copolymerization of acrylonitrile-butadiene rubber (NBR) and polyvinyl chloride (PVC) The solution is blended and cast into a polymer film having a multi-phase structure. The multi-phase polymer film contains polymer lithium salt, plasticizer or plasticizer absorbs inorganic lithium salt organic solution becomes polymer single ion conductor or double ion conductor, the room temperature conductivity is greater than 3.0 × 10 ~ 4S.cm-1 and 2.06 × 10-3s-cm-1. The plasticized PVC in the film continuously functions as a mechanical support, so that the plasticized multi-phase polymeric ion conductor has a mechanical strength of greater than 9.8 × 10 5 Pa.