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進行了甲基環戊烷以及二甲基環戊烷異構體的混合物的重整試驗.研究了過程條件對各種反應轉化深度的影響与各種反應的動力學.升高溫度能加速芳烴化反應,及較少加速氫解.反應時間延長能使這兩種反應都增加.異構化為反應的中間階段,很少受反應條件改變的影響.根據各種反應的微分速度計算出速率常數,並指出芳烴生成及總轉化服從被芳烴阻抑的一次反应式,而氫解則服從無產品阻抑的一次式.根據動力學數據及鉑重整產品的詳細分析結果,提出了甲基環戊烷及二甲基環戊烷在鉑重整條件下的轉化流程.
The reforming experiments of the mixture of methylcyclopentane and dimethylcyclopentane isomers were carried out.The influence of process conditions on the depth of various reactions and the kinetics of various reactions were studied.It was found that the higher temperature could accelerate the aromatic reaction , And less accelerated hydrogenolysis.The longer the reaction time, both of these reactions increase.The isomerization is the intermediate stage of the reaction and is less affected by changes in the reaction conditions.The rate constant is calculated based on the differential velocities of the various reactions and It is pointed out that the formation and total conversion of aromatics are subject to the first reaction mode suppressed by aromatics, whereas the hydrogenolysis obeys the first order without product inhibition.Based on the kinetic data and the detailed analysis results of platinum reformate, methylcyclopentane And dimethylcyclopentane conversion process in the platinum reforming conditions.