Two bipolar materials,2,5-bis(2-(9H-carbazole-9-yl)phenyl)-1,3,4-oxadiazole(o-CzOXD)and 2,5-bis(2-(3’,6’-di-tert-butyl-9H-carbazole-9-yl)phenyl)-1,3,4-oxadiazole(tBu-o-CzOXD),were synthesized according to reported methods.In parallel study,it was demonstrated that introduction of inert tert-butyl group improved material thermal stability,even though this modification only had a slight influence to the photophysical and electrochemical properties of these materials.A comparative study focusing on effects of heat treatment was carried out on the quartz glass substrates with vacuum deposited films containing one of the bipolar host doped with 6 wt%fac-tris(2-phenylpyridinato-N,C2’)iridium(Ir(ppy)3).Results show that when the two samples were heated,the absorption,emission,and photo images of the host:dopant system changed,with the o-CzOXD suffering more severe degradation under high temperature,which is consistent with their thermal stability.In addition,it was proved that the high temperature-annealed host:dopant system can enhance the emission of the dopant.This finding was used as a guideline to improve our device performance.We fabricated two types of phosphorescent organic light-emitting devices(PhOLEDs),one was based on o-CzOXD,the other was based on tBu-o-CzOXD.They had analogous structure.We investigated the effect of heat on device performance by selectively annealing.Although these two freshly prepared devices exhibited similar performance,when annealed at 90°C for 10 min,the OLEDs based on tBu-o-CzOXD showed significant performance enhancement,which can be attributed to the observation that annealing Ir(ppy)3 doped host can change film morphology and enhance the dopant emission.The maximum efficiencies of the freshly prepared tBu-o-CzOXD device were 25.8 cd A-1,23.1lm W-1,and 9.3%;whereas those for annealed device were 47.0 cd A-1,42.2 lm W-1,and 13.4%. Two bipolar materials 2,5-bis (2- (9H-carbazole-9-yl) phenyl) -1,3,4- oxadiazole (o-CzOXD) and 2,5-bis phenyl-1,3,4-oxadiazole (tBu-o-CzOXD), were synthesized according to reported methods. In parallel study, it was said that introduction of inert tert-butyl group improved material thermal stability, even though this modification only had a slight influence to the photophysical and electrochemical properties of these materials. A comparative study focusing on effects of heat treatment was carried out on the quartz glass substrates with vacuum deposited films containing one of the bipolar host doped with 6 wt% fac-tris (2-phenylpyridinato-N, C2 ’) iridium (Ir (ppy) 3). Results show that when the two samples were heated, the absorption, emission, and photo images of the host: dopant system changed, with the o-CzOXD suffering more severe severe under high temperature, which is consistent with their thermal stability. In addition, it was proved that the high temp erature-annealed host: dopant system can enhance the emission of the dopant. This finding was used as a guideline to improve our device performance. We fabricated two types of phosphorescent organic light-emitting devices (PhOLEDs), one was based on o-CzOXD , the other was based on tBu-o-CzOXD. The had had analogous structure. We investigated the effect of heat on device performance by alternatively annealing. Although these two freshly prepared devices showed similar performance, when annealed at 90 ° C for 10 min, the OLEDs based on tBu-o-CzOXD showed significant performance enhancement, which can be attributed to the observation that annealing Ir (ppy) 3 doped host can change the film morphology and enhance the dopant emission.The maximum efficiencies of the freshly prepared tBu-o CzOXD devices were 25.8 cd A-1, 31 .1 lm W-1, and 9.3%; those those for annealed devices were 47.0 cd A-1, 42.2 lm W-1, and 13.4%.