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在聚乙二醇(PEO)存在下,CaCl2和Na2CO3反应得多晶形碳酸钙沉淀,X-衍射显示主要为文石型结构,并随着PEO/Ca摩尔比的增大,晶体颗粒变小。结果表明,聚合物对碳酸钙晶核的形成和晶体的生长有很大影响。本文还对其形成机理进行了初步探讨。
In the presence of polyethylene glycol (PEO), CaCl2 and Na2CO3 reacted to form polymorphic calcium carbonate, X-ray diffraction showed a mainly aragonitic structure, and with the increase of PEO / Ca molar ratio, the crystal particles became smaller. The results show that the polymer has a great influence on the formation of calcium carbonate nuclei and crystal growth. This article also made a preliminary discussion of its formation mechanism.