论文部分内容阅读
烯丙基胺类化合物是有机化学中的重要合成中间体,亚硝基-烯(nitroso-ene)反应是合成这类化合物最为高效的方法之一.在一些天然产物和药物分子的全合成中,亚硝基-烯反应也往往作为关键步骤.这篇综述主要介绍了亚硝基–烯反应的发展、应用以及机理研究方面的进展.
Allylamine compounds are important synthetic intermediates in organic chemistry and one of the most efficient methods for the synthesis of these compounds is the nitroso-ene reaction.In some syntheses of natural products and drug molecules , Nitroso-ene reaction is also often taken as the key step.This review mainly introduces the development of nitroso-ene reaction, application and mechanism of progress.