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用具有恒定温度环境的反应热量计 ,通过溶解热法及针对 Zn Cl2 与对甲基苯胺配位反应所设计的热化学循环 ,得到该配位反应的标准反应焓 ,并求得配合物 Zn(p- tol) 2 Cl2 的标准生成焓
The standard reaction enthalpies of the complexation reaction were obtained by the thermosensitive cycle designed by the reaction of solution heat and the coordination reaction between ZnCl2 and p-methylaniline, using the reaction calorimeter with a constant temperature environment. The complex Zn ( p-tol) 2 Cl2 standard enthalpy of formation