Morphology and Mechanical Properties of Nylon 6/PBT Blends Compatibilized with Styrene/Maleic Anhydr

来源 :Chemical Research in Chinese Universities | 被引量 : 0次 | 上传用户:yongqingf
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The mechanical properties and dynamic mechanical properties of blends composed of Nylon 6 and poly(butylenes terephthalate)(PBT),with styrene/maleic anhydride(SMA)as compatibilizer,were studied.The observation on the morphologies of the etched surfaces of the cryogenically fractured specimens via scanning electron microscopy(SEM)demonstrated that in the compatibilized Nylon 6/PBT blends,there exists a finer and more uniform dispersion induced by the in-situ interfacial chemical reactions during the preparation than that in the corresponding uncompatibilized blends.On the other hand,the overall mechanical properties of the compatibilized blends could be remarkably improved compared with those of the uncompatibilized ones.Moreover,increasing the amount of the compatibilizer SMA leads to a more efficient dispersion of the PBT phase in Nylon 6/PBT blends.Furthermore,there exists an optimum level of SMA added to achieve the maximum mechanical properties.As far as the mechanism of this reactive compatibilization is concerned,the enhanced interfacial adhesion is necessary to obtain improved dispersion,stable phase morphology,and better mechanical properties. The mechanical properties and dynamic mechanical properties of blends composed of Nylon 6 and poly (butylenes terephthalate) (PBT), with styrene / maleic anhydride (SMA) as compatibilizer, were studied. The observation on the morphologies of the etched surfaces of the cryogenically fractured specimens via scanning electron microscopy (SEM) that that the compatibilized Nylon 6 / PBT blends, there exists a finer and more uniform dispersion induced by the in-situ interfacial chemical reactions during the preparation than that in uncomplatibilized blends. On the other hand, the overall mechanical properties of the compatibilized blends could be remarkably improved compared to those of the uncompatibilized ones. More over, increasing the amount of the compatibilizer SMA leads to a more efficient dispersion of the PBT phase in Nylon 6 / PBT blends. Futurerther, there exists an optimum level of SMA added to achieve the maximum mechanical properties. As far as the mechanism of this react ive compatibilization is concerned, the enhanced interfacial adhesion is necessary to obtain improved dispersion, stable phase morphology, and better mechanical properties.
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