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研究了两种带季铵正离子的吡咯衍生物在乙腈中的电聚合.用Fe(CN)3-6离子测定了所制得聚合物修饰电极的阴离子交换能力,并研究了羧基取代酞菁钴低聚物——八羧基酞菁钴(CoOCPC)交换到预聚的导电膜中而制得的修饰电极对氧的电还原催化作用.实验表明此类电极具有较好的催化活性,最终产物主要是水.
The electropolymerization of two azole derivatives with quaternary ammonium cation in acetonitrile was studied. The anion exchange ability of the prepared polymer modified electrode was measured with Fe (CN) 3-6 ions. The effect of cobalt-substituted phthalocyanine cobalt-cobalt phthalocyanine cobalt (CoOCPC) exchange on the prepolymerization of conductive Film in the modified electrode of the oxygen reduction catalytic effect. Experiments show that such electrodes have good catalytic activity, the final product is mainly water.