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六氢吡啶基二硫代甲酸钠盐、氯化亚铁及四硫代钼酸铵在二甲基甲酰胺及二氯甲烷中,经一步自兜反应,分别得到了[MoFe_3S_4(C_5H_(10)NCSS)_5]DMF及[MoFe_3S_4(C_5H_(10)NCSS)_5]CH_2Cl_2。通过X射线衍射测定了后者的晶体结构,比较了它与[MoFe_3S_4(Et_2NCSS)_5]~-结构特点的异同,同时研究了反应物摩尔比对产物的影响以及溶剂分子的置换反应。
(NH4) 3, hexahydropyridyl dithiocarboxylate sodium salt, ferrous chloride and ammonium tetrathiomolybdate in dimethylformamide and dichloromethane, one-step self-pocket reaction, were obtained [MoFe_3S_4 (C_5H_ (10) NCSS ) _5] DMF and [MoFe_3S_4 (C_5H_ (10) NCSS) _5] CH_2Cl_2. The crystal structure of the latter was determined by X-ray diffraction. The similarities and differences between [MoFe_3S_4 (Et_2NCSS) _5] ~ and its structure were also investigated.