The Effect of Non-Framework Aluminum on the Stability and Activity of REY Zeolite

来源 :China Petroleum Processing and Petrochemical Technology | 被引量 : 0次 | 上传用户:zhlxqfenglin
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The present study is focused on the influence of a routine step, washing, following the preparation of calcined rare earth exchanged Y zeolite, on its hydrothermal stability. The hydrothermal stability of REY products, which were washed by different reagents, was observed and characterized by XRD, ICP, NMR, etc. The results reveal that the amount and the chemical type of the acidic media used for washing can significantly influence the content of remaining non-framework aluminum (NFA) and consequently further affect the hydrothermal stability of the washed REY products. The content of remaining non-framework aluminum can be well correlated with the crystallinity of REY products. The present study is focused on the influence of a routine step, washing, following the preparation of calcined rare earth exchanged Y zeolite, on its hydrothermal stability. Was hydrothermal stability of REY products, which were washed by different reagents, was observed and characterized by XRD, ICP, NMR, etc. The results reveal that amount and the chemical type of the acidic media used for washing can significantly influence the content of remaining non-framework aluminum (NFA) and preferably further the hydrothermal stability of the washed REY products. The content of remaining non-framework aluminum can be well correlated with the crystallinity of REY products.
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