本文用定标粒子理论与玻恩方程联合,来预测在非水溶剂中准溶电解质的溶度积常数,所得结果与文献报导的实验数据作了比较,表明预测结果是满意的。从而在缺乏非水溶剂数据的情况下,提供了一种切实可行的预测方法。本文还拟合了一组AgX在水、甲醇、乙醇和正丙醇中pKs的计算公式,其计算值对实验值的相对误差不超过±1.1％。 In this paper, the calibration particle theory and the Born equation were combined to predict the solubility product constant of the electrolyte in nonaqueous solvents. The results obtained were compared with the experimental data reported in the literature, indicating that the prediction results are satisfactory. Thus providing a viable forecasting method in the absence of non-aqueous solvent data. In addition, a series of formulas for calculating the pKs of AgX in water, methanol, ethanol and n-propanol were also fitted. The relative error between calculated and experimental values ​​was less than ± 1.1%.