【摘 要】
：
McAllister三体模型的关联性限制了其拓展应用,本文在搜集文献中14类系列型烃类混合物黏度实验数据的基础上,拟合得到了其模型参数.分析发现,McAllister三体模型的两个待定参数(v12与v21)与等效沸点(Tbij)及实验温度(T)间存在一定的规律,由此获得了模型参数的定量推算关系,进而建立了一种具有预测同系列烃类混合物黏度的通用化McAllister三体模型.将新模型的计算结果与实验值进行比较表明,对于所有二元体系的总体平均相对偏差为0.79％,最大相对偏差为7.22％.
【机 构】
：
河北大学质量技术监督学院,保定071002
论文部分内容阅读
McAllister三体模型的关联性限制了其拓展应用,本文在搜集文献中14类系列型烃类混合物黏度实验数据的基础上,拟合得到了其模型参数.分析发现,McAllister三体模型的两个待定参数(v12与v21)与等效沸点(Tbij)及实验温度(T)间存在一定的规律,由此获得了模型参数的定量推算关系,进而建立了一种具有预测同系列烃类混合物黏度的通用化McAllister三体模型.将新模型的计算结果与实验值进行比较表明,对于所有二元体系的总体平均相对偏差为0.79％,最大相对偏差为7.22％.
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