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A new complex of N,N?-bis(p-nitrophenyl)-2,2?-(p-phenylene-dioxy) diacetamide DMF monohydrate, C25H25N5O9·H2O (Mr = 557.52), has been synthesized and its structure was determined by X-ray crystallography method. The crystal belongs to monoclinic system, space group P21/c with a = 7.2812, b = 25.5894, c = 14.3434 ?, β = 91.110(1)o, V = 2672.0(2) ?3, Dc = 1.386 g/cm3, F(000) = 1168, μ = 0.109 mm-1 and Z = 4. The final R = 0.0493 and wR = 0.1173 for 3389 observed reflections with I > 2σ(I). The asymmetric unit of the title complex consists of monomeric N,N?-bis(p-nitrophenyl)-2,2?-(p-phenyleneioxy)diacetamide 1, one DMF and one water molecule, which are incorporated during recrystallization. The molecules are linked into a three-dimensional network by π…π interactions as well as intermolecular interactions among DMF, water molecule and 1.
A new complex of N, N? -bis (p-nitrophenyl) -2,2? - (p-phenylene-dioxy) diacetamide DMF monohydrate, C25H25N5O9 H2O (Mr = 557.52), has been synthesized and its structure was determined by X-ray crystallography method. The crystal belongs to monoclinic system, space group P21 / c with a = 7.2812, b = 25.5894, c = 14.3434?, Β = 91.110 (1) o, V = 2672.0 = 1.386 g / cm3, F (000) = 1168, μ = 0.109 mm-1 and Z = 4. The final R = 0.0493 and wR = 0.1173 for 3389 observed reflections with I> 2σ (I). The asymmetric unit of the title complex consists of monomeric N, N -bis (p-nitrophenyl) -2,2- (p-phenyleneoxy) diacetamide 1, one DMF and one water molecule, which are incorporated during recrystallization. The molecules are linked into a three -dimensional network by π ... π interactions as well as intermolecular interactions among DMF, water molecule and 1.