在水热条件下2个配体特戊酸(piv H)和1-H-咪唑[4,5-f][1,10]-菲咯啉(IP)和稀土金属反应得到了6个稀土配合物[Ln(piv)3(IP)2],(Ln=Nd(1),Eu(2),Gd(3),Tb(4),Dy(5),Ho(6))。结果显示,2个混合配体和不同的稀土金属形成了6个相似的零维结构,进而通过N-H…O氢键和π-π堆积作用,形成一维链状结构。6个配合物均用元素分析、粉末衍射(PXRD)、红外光谱(FTIR)进行了表征,且对配合物2和4的荧光性质及1和2的热稳定性进行了详细的分析。 Two ligands, piv H and 1-H-imidazo [4,5-f] [1,10] -phenanthroline (IP) and rare earth metals were reacted under hydrothermal conditions to obtain six rare earth The complexes [Ln (piv) 3 (IP) 2], (Ln = Nd (1), Eu (2), Gd (3), Tb (4), Dy (5), Ho (6)). The results show that two hybrid ligands and different rare earth metals form six similar zero - dimensional structures, and then form a one - dimensional chain structure through N-H ... O hydrogen bonds and π-π stacking. The six complexes were characterized by elemental analysis, powder diffraction (PXRD) and infrared spectroscopy (FTIR). The fluorescence properties of complexes 2 and 4 and the thermal stability of 1 and 2 were analyzed in detail.