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A novel hexanuclear copper-indium thiolate complex,[(InCl)2(OMe)(μ-OMe)2(μ3-OMe)(μ-SPrn)2(CuPPh3)]2 1,was synthesized from the reaction of NaSPrn,InCl3 and [Cu(MeCN)4][PF6] in the presence of Ph3P and characterized by single-crystal X-ray diffraction.It c