【摘 要】
：
Six series of meso-tetrakis (4-n-alkanoyloxyphenyl) porphyrin Co and Ni complexes (12 kinds) were reported. Nine of the compounds were found to exhibit liquid c
【机 构】
：
College of Materials Science and Engineering,Department of Chemistry
【基金项目】
：
国家自然科学基金;山东省自然科学基金;Doctor Foundation of Shandong University of Technology;山东大学校科研和教改项目;山东省教育基金
论文部分内容阅读
Six series of meso-tetrakis (4-n-alkanoyloxyphenyl) porphyrin Co and Ni complexes (12 kinds) were reported. Nine of the compounds were found to exhibit liquid crystal properties and display a hexagonal columnar discotic columnar (Colh) phase. Molecular structure of all synthesized compounds was confirmed by IR, UV, MS, 1H NMR, and elemental analysis. These liquid crystalline compounds have been studied by cyclic voltammetry, luminescence, and surface photovoltage spectroscopy.
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