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The mechanism of separating hematite from kaolinite by shear-flocculation and the reason responsible for the selectivity of shear-flocculation was studied by using diffuse reflectance infrared Fourier transform (DRIFT) spec-troscopy, which was found to be effective for analysing adsorbed oleate species on the highly absorbing mineral hematite. The spectra suggest that chemisorption of oleate on hematite took place under shear-flocculation condition and that the chemisorbed species was bridged bidentate, corresponding to a peak at 1580 cm-1. Dimers of oleic acid, corre-
The mechanism of separating hematite from kaolinite by shear-flocculation and the reason responsible for the selectivity of shear-flocculation was studied by using diffuse reflectance infrared Fourier transform (DRIFT) spec-troscopy, which was found to be effective for analysing adsorbed oleate species on the highly suggestive mineral hematite. The spectra suggest that chemisorption of oleate on hematite took place under shear-flocculation condition and that the chemisorbed species was bridged bidentate, corresponding to a peak at 1580 cm- 1. Dimers of oleic acid, corre-