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用红外光谱法对二苯基膦系列配体及其分别与Cu(BF_4)_2和Cu(C_3H_7COO)_2。形成的系列配位化合物进行了研究,讨论了谱带的归属和Cu(Ⅰ)配合物形成前后相关谱带的变化规律,并参照元素分析、X-射线粉末衍射分析和热重分析的结果,讨论了所形成配位化合物的可能的结构模式。
The infrared spectra of diphenylphosphine ligands and their interaction with Cu (BF_4) _2 and Cu (C_3H_7COO) _2. The formation of a series of coordination compounds were studied. The variation of the bands and the related bands before and after the formation of Cu (Ⅰ) complexes were discussed. With reference to the results of elemental analysis, X-ray powder diffraction and TG analysis, The possible structural modes of the formed coordination compounds are discussed.