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从对(三甲硅基)甲苯开始,将苄基中的甲基溴化成溴甲基,从而制得对(三甲硅基)苄基取代的乙酰乙酸乙酯,丙二酸乙酯和氰化物等,应用Sommlet反应制得醛. 将对(三甲硅基)甲苯氧化成相应的羧酸后,用亚硫酰氯处理,加入氨水即得对(三甲硅基)苯甲酰胺.应用类似方法,制得对(三苯硅基)苯甲酸、二甲基二(对羧基苯基)硅烷和二苯基二(对羧基苯基)硅烷的一些酰胺和酯.在用亚硫酰氯处理时,未发现硅-碳键的断裂现象.
Starting from (trimethylsilyl) toluene, the methyl group in the benzyl group is brominated to a bromomethyl group, thereby producing ethyl (ethylsilyl) ethyl acetoacetate, ethyl malonate and cyanide , The Sommlet reaction was used to produce the aldehyde. After the (trimethylsilyl) toluene was oxidized to the corresponding carboxylic acid, it was treated with thionyl chloride, and then added with aqueous ammonia to obtain the (trimethylsilyl) benzamide. In a similar manner, Some of the amides and esters of (triphenylsilyl) benzoic acid, dimethyldi (p-carboxyphenyl) silane and diphenyldi (p-carboxyphenyl) silane.In the treatment with thionyl chloride, no silicon - Carbon bond breaking phenomenon.