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用低压汞灯照射,研究了n-C_6H_(14)-TBP体系的光化学反应。通过与γ辐解结果对比和动力学分析,证实了γ辐解n-C_6H_(14)-TBP体系中,激发能转移是能量传递的主要形式,并讨论了亚激电子在能量传递中的作用。
The photochemical reaction of n-C_6H_ (14) -TBP system was studied by using low-pressure mercury lamp. Through the comparison with the γ-radiation results and the kinetic analysis, it was confirmed that the transfer of excitation energy is the main form of energy transfer in the γ-radiation n-C_6H_ (14) -TBP system and the role of the sub-excited electrons in energy transfer .