在戴安邦教授的指导下 ,我们实验室多年来在室温、近室温条件下采用固相反应法合成了一系列原子簇化合物 ,本文则对用此方法合成的Mo(W ) /S/Cu(Ag)原子簇化合物进行了分类和总结 ,并探讨了固相反应合成原子簇化合物的成簇规律和成簇机理。同时本文还概括和总结了Mo(W ) /S/Cu(Ag)原子簇化合物的光限制效应 ,三阶非线性吸收与非线性折射等光学性质 ,初步探讨了Mo(W ) /S/Cu(Ag)原子簇化合物的结构与光学性质之间的关系 Under the guidance of Professor Dai Anbang, our laboratory has synthesized a series of atomic cluster compounds by solid-state reaction at room temperature and near room temperature for many years. In this paper, Mo (W) / S / Cu ) Clusters were classified and summarized, and the clustering mechanism and clustering mechanism of the solid cluster reaction were discussed. At the same time, this paper also summarizes and summarizes the optical confinement effect, third-order nonlinear absorption and nonlinear refraction of Mo (W) / S / Cu (Ag) cluster compounds. (Ag) cluster compounds of the structure and optical properties of the relationship between