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用锌粉、硫粉以及 1.10—邻菲罗啉在N ,N—二甲基甲酰胺溶剂中直接反应得黄色标题化合物 .X射线结晶学表征该分子含四面体配位的ZnS2 N2 核心 .结晶学参数 :三斜晶系 ,Z=2 ,P i,a =0 .8159(2 )nm ,b =0 .94 85(2 )nm ,c =1.1997(2 )nm ,α =110 .0 0 (3)° ,β=99.2 2 (3)°,γ=10 0 .57(3)°,V=0 .832 (0 .173)nm3 .标题化合物经四圆衍射、元素分析测试 ,表明其化合物化学式为Zn(C12 H8N2 )S6.标题化合物经紫外、红外光谱归属、循环伏安、热分析以及荧光性能研究表明 ,在DMF中激发波长为 2 75nm处具有荧光性能 ,温度低于 199.6℃ ,晶体十分稳定 .
The title compound was directly synthesized from zinc powder, sulfur powder and 1.10-phenanthroline in N, N-dimethylformamide solvent, X-ray crystallography characterization of the tetrahedral coordinated ZnS2N2 core. The parameters of the triclinic system are as follows: triclinic system, Z = 2, P i, a = 0 .8159 (2) nm, b = 0.9485 (2) nm, c = 1.1997 (3) °, β = 99.2 2 (3) °, γ = 10 0 .57 (3) °, V = 0 .832 (0 .173) nm3. The title compound was characterized by four-circle diffraction and elemental analysis. The chemical formula of the compound was Zn (C12 H8N2) S6. The title compounds were characterized by UV-IR, cyclic voltammetry, thermal analysis and fluorescence studies. The results showed that the excitation wavelength was at 2 75 nm in DMF with fluorescence below 199.6 ℃, Crystal is very stable.