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合成了配合物[Cu(C9H7NO3)(phen)2](OH)·4H2O·0.75CH3OH(其中C9H7NO3=马尿酸,phen=邻菲啰啉),并利用X-射线单晶衍射仪确定了其结构。该配合物属三斜晶系,空间群为P。在配合物中,每个Cu(Ⅱ)离子与一个马尿酸阴离子的一个羧基氧和两个邻菲啰啉的四个氮原子配位,形成五配位的畸变的三角双锥结构。配体马尿酸的羧基O原子与配体邻菲啰啉芳环上的H原子通过氢键连接成三维网状结构。
The complex [Cu (C9H7NO3) (phen) 2] (OH) · 4H2O · 0.75CH3OH (C9H7NO3 = hippuric acid, phen = phenanthroline) was synthesized and characterized by X-ray single crystal diffraction . The complex is triclinic, space group P In the complex, each Cu (II) ion coordinates with one carboxyl oxygen of one hippuric acid anion and four nitrogen atoms of two phenanthrolines to form a five-coordinate distorted triangular bipyramidal structure. Ligands uric acid carboxyl O atom and the ligand phenanthroline aryl ring H atoms through hydrogen bonds into a three-dimensional network structure.