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The FT-IR and FT-Raman spectra of complexes (C5H5)2TiCl2(Ⅰ), (C5H4Me)2TiCl2 (Ⅱ) and (C5HMe4)2TiCl2(Ⅲ) have been obtained and discussed. The FT-Raman spectral data pro- vide some new vibrational information about complexes (Ⅰ), (Ⅱ) and (Ⅲ). The assignments of cyclopentadienyl vibrational modes and skeletal vibrational modes have been made.
The FT-IR and FT-Raman spectra of complexes (C5H5) 2TiCl2 (Ⅰ), (C5H4Me) 2TiCl2 (Ⅱ) and (C5HMe4) 2TiCl2 (Ⅲ) have been obtained and discussed. The FT-Raman spectral data pro- vide some new vibrational information about complexes (Ⅰ), (Ⅱ) and (Ⅲ). The assignments of cyclopentadienyl vibrational modes and skeletal vibrational modes have been made.