A Simple Deposition Method for Self-Assembling Single Crystalline Hybrid Perovskite Nanostructures

来源 :Chinese Physics Letters | 被引量 : 0次 | 上传用户:qq1036191963
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
A sequential deposition method is developed, where the hybrid organic-inorganic halide perovskite(CH_3 NH_3Pb(I_(1-x)Br_x)_3) is synthesized using precursor solutions containing CH_3NH_3I and PbBr_2 with different mole ratios and reaction times. The perovskite achieved here is quite stable in the atmosphere for a relatively long time without noticeable degradation, and the perovskite nanowires are proved to be single crystalline structure, based on transmission electron microscopy. Furthermore, strong red photoluminescence from perovskite is observed in the wavelength range from 746 nm to 770 nm with the increase of the reaction time, on account of the exchanges between I-ions and Br~-ions in the perovskite crystal. Lastly, the influences of concentration and reaction time of the precursor solutions are discussed, which are important for evolution of hybrid perovskite from nanocuboid to nanowire and nanosheet. The sequential deposition method is developed, where the hybrid organic-inorganic halide perovskite (CH_3NH_3Pb (I_ (1-x) Br_x) _3) is synthesized using precursor solutions containing CH_3NH_3I and PbBr_2 with different mole ratios and reaction times. The perovskite achieved here is quite stable in the atmosphere for a relatively long time without noticeable degradation, and the perovskite nanowires are proved to be single crystalline structure, based on transmission electron microscopy. Furthermore, strong red photoluminescence from perovskite is observed in the wavelength range from 746 nm to 770 nm with the increase of the reaction time, on account of the exchanges between I-ions and Br ~ -ions in the perovskite crystal. Lastly, the influences of concentration and reaction time of the precursor solutions are discussed, which are important for evolution of hybrid perovskite from nanocuboid to nanowire and nanosheet.
其他文献
丙型肝炎病毒(HCV)是一种正链单股的RNA病毒,其基因结构与瘟病毒属和黄病毒属相似。HCV的复制需经过形成一个负链RNA的中间型,通过这种负链RNA的中间型编码病毒正链基因组。
We recognize the stochastic collisions of dopamine contained phospholipid vesicle on carbon fiber nanoelectrode, extending the observation of discrete collision
三千农民托起石林鞋业集团云南石林鞋业集团公司注重向农村扩散技术、资金和产品,国有企业与乡镇企业联手拓展橡胶加工产业规模,使蒙自县成为远近闻名的“鞋城”。蒙自县原是仅
规律一:11248规律。此规律是当烷基中碳原子的个数分别为1,2,3,4,5时,其一取代物的同分异构体数目分别是1,1,2,4,8种。例1(1)分子式为C_5H_(11)Cl的同分异构体共有(不考虑立
a-干扰素(IFN-α)短程疗法能降低丁型肝炎病人血清转氨酶和丁型肝炎病毒(HDV)RNA,但维持疗效短。本文报告IFN-α长程(12个月)治疗HDV感染的结果。作者选择慢性HDV感染患者11
[问]民用建筑安装预应力空心楼板时,经常由于空心板过宽造成一侧压墙。这样,与设计图纸不符,质量检查部门也不允许,但究竟为什么不允许,请给予指教。(青岛市马德臣)[答]楼板
笔者认为,优则奖励,劣则批评,是应该的,但要讲求一个“活”字。从两个方面来看,一是对于优者,他们做了别人在工作中没有做到的服务,比其他员工表现得更为投入,应给予奖励;但
有一位爱吃炸面圈的国王,他吃起炸面圈来没够,而且越吃越多,人们都叫他“炸画圈国王”。为了供给国王吃炸面圈,王国里所有的农田不得不改成面包房。一天,国王一照镜子,发现
【捕捉问题】“这是我的虾!”一句看似普通的话,却让一位母亲精神彻底崩溃。在此,向读者转述一个故事:一位高三的学生,父母离异,母亲是环卫工人。他从小就跟着母亲过,日子过
本研究以黄土高原粗泥沙集中来源区面积最大且连续的区域(即北起皇甫川流域南至佳芦河流域地区)为研究对象,以1960~1999年为研究时段,分析了该区内水沙变化特征。结果表明:降