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A newly developed pure rolling fatigue test rig with three contact points for bearing balls was used to perform rolling contact fatigue (RCF) tests. The fatigue properties of GCr15 steel balls and two kinds of Si3N4 ceramic balls (GSN-200 and NBD-200) produced with different technologies were compared. Ball surfaces were examined after failure with optical microscope and scanning electron microscope (SEM). It was identified by tests that the failure mode of ceramic balls was surface spall. The main factor of ceramic ball failure was principal tensile stress. Life tests data, summarized in accordance with the Weibull theory, showed that the life of GSN-200 balls was close to that of GCr15 balls, whereas the life of NBD-200balls was much longer than those of GSN-200 and GCr15. Under the same working condition, the temperature rise of all ceramic balls was lower than that of steel balls, and their crack propagation rates were slower than that of steel balls.