论文部分内容阅读
本文用核磁共振等方法研究了稀土络合物和碱金属盐中的七甲茚基的质子化或氘化反应、亲核取代反应及络合物中稀土离子的还原反应。七甲茚基络合物比相应的茂基或茚基化合物更易与盐进行上述反应。三氘代七甲茚基在氘化反应中显示了同位素效应。
In this paper, the protonation or deuteration of heptamethyladenyl in the rare earth complexes and alkali metal salts, the nucleophilic substitution reaction and the reduction of rare earth ions in the complexes were studied by means of NMR. The heptamethindenyl complex is more easily reacted with the salt than the corresponding cyclopentadienyl or indenyl compound. Deuterated heptamethyladenyl shows isotope effect in deuteration reaction.