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首次用碳酸铷与NTO在水溶液中直接合成了Rb+ 与NTO- 的配合物。采用元素分析和化学分析确定配合物的组成为Rb(NTO)·(H2 O)。用X 射线粉末衍射谱的测试与分析对该配合物进行了结构和性质的表征。给出了FTIR和Raman光谱 ,分析了各种谱线的归属。从结构角度讨论了配合物中不同键的形成。
For the first time, Rb + and NTO- complexes were directly synthesized from rubidium carbonate and NTO in aqueous solution. The composition of the complex was determined to be Rb (NTO) · (H 2 O) using elemental analysis and chemical analysis. The structure and properties of the complex were characterized by X-ray powder diffraction spectrometry. The FTIR and Raman spectra are given, and the assignments of various spectral lines are analyzed. From the structural point of view, the formation of different bonds in the complex was discussed.